Thanks for all the tips. I have went back to messing with Photoshop, and found a way to get some pretty nice result's.

First just draw whatever you want to make, I am doing a logo for a friend. Then once you have that layer done with whatever, click on 3D at the top > new extrusion from selected layer. (I also duplicated and merged a few time's to make it a darker outline)

Next, click on the extrusion to make it active. Change the "Extrusion depth" to 0.1 and hit enter. This will make it a small extrusion and file to work with in other program's.

Next, click on the 3D tab at the top again, and click Render. Wait for it to finish rendering. This makes the edges very smooth. When it is done, click on 3D tab once more and "Export 3D layer", and save the STL file. My file came out to 244kb small, and perfect to bring into other programs to edit from there. Check out a few photo's compared to before. I feel this could be used for many, many thing's.

hat01.jpghat3.jpghat1.jpghat2.jpghat33.jpg

Hopefully this helps someone out